Coherent band excitations in CePd<sub>3</sub>: A comparison of neutron scattering and ab initio theory.
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Abstract |
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In common with many strongly correlated electron systems, intermediate valence compounds are believed to display a crossover from a high-temperature regime of incoherently fluctuating local moments to a low-temperature regime of coherent hybridized bands. We show that inelastic neutron scattering measurements of the dynamic magnetic susceptibility of CePd3 provides a benchmark for ab initio calculations based on dynamical mean field theory. The magnetic response is strongly momentum dependent thanks to the formation of coherent f-electron bands at low temperature, with an amplitude that is strongly enhanced by local particle-hole interactions. The agreement between experiment and theory shows that we have a robust first-principles understanding of the temperature dependence of f-electron coherence. |
Year of Publication |
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2018
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Journal |
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Science (New York, N.Y.)
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Volume |
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359
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Issue |
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6372
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Number of Pages |
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186-191
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Date Published |
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2018
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ISSN Number |
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0036-8075
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DOI |
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10.1126/science.aan0593
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Short Title |
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Science
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