Sensitized near infrared emission through supramolecular d → f energy transfer within an ionic Ru(ii)-Er(iii) pair.
| Author | |
|---|---|
| Abstract |
:
The newly synthesized ionic triple salt Ru-Er, {[RuII(bpy)2(dbim)][ErIII(hfac)4][CF3COO]·H2O} (bpy = 2,2'-bipyridine; hfac- = hexafluoroacetylacetonate; dbim = 2,2'-dibenzimidazole) exhibits near-infrared (NIR) emission at 1535 nm by intermolecular Ru → Er (d → f) energy transfer across supramolecular interactions when pumped within the Ru(ii) 3MLCT band. It is the first such observation for a transition metal-lanthanide ionic pair. |
| Year of Publication |
:
2018
|
| Journal |
:
Dalton transactions (Cambridge, England : 2003)
|
| Date Published |
:
2018
|
| ISSN Number |
:
1477-9226
|
| URL |
:
http://dx.doi.org/10.1039/c7dt04041e
|
| DOI |
:
10.1039/c7dt04041e
|
| Short Title |
:
Dalton Trans
|
| Download citation |
